3,3,5-Trimethylcyclohexanone
- CasNo:873-94-9
Product Description
Purity 99% Min 3,3,5-Trimethylcyclohexanone 873-94-9 Spot Supply with Safe Transportation
- Molecular Formula: C9H16O
- Molecular Weight: 140.225
- Appearance/Colour: clear colourless to very slightly yellow liquid
- Vapor Pressure: 0.582mmHg at 25°C
- Melting Point: -10 °C
- Refractive Index: n20/D 1.445(lit.)
- Boiling Point: 188.8 °C at 760 mmHg
- Flash Point: 64 °C
- PSA： 17.07000
- Density: 0.888 g/cm3
- LogP: 2.40170
3,3,5-Trimethylcyclohexanone(Cas 873-94-9) Usage
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Synthesis Reference(s) |
The Journal of Organic Chemistry, 43, p. 4647, 1978 DOI: 10.1021/jo00418a024Synthetic Communications, 15, p. 759, 1985 DOI: 10.1080/00397918508063869Tetrahedron Letters, 29, p. 5471, 1988 DOI: 10.1016/S0040-4039(00)80789-3 |
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Flammability and Explosibility |
Notclassified |
InChI:InChI=1/C9H16O/c1-7-4-8(10)6-9(2,3)5-7/h7H,4-6H2,1-3H3/t7-/m1/s1
873-94-9 Relevant articles
Could the energy cost of using supercritical fluids be mitigated by using CO2 from carbon capture and storage (CCS)?
Stevens, James G.,Gomez, Pilar,Bourne, Richard A.,Drage, Trevor C.,George, Michael W.,Poliakoff, Martyn
, p. 2727 - 2733 (2011)
This article explores the possibility of...
Water-soluble dendritic architectures with carbohydrate shells for the templation and stabilization of catalytically active metal nanoparticles
Kraemer, Michael,Perignon, Nelly,Haag, Rainer,Marty, Jean-Daniel,Thomann, Ralf,Viguerie, Nancy Lauth-De,Mingotaud, Christophe
, p. 8308 - 8315 (2005)
Hyperbranched poly(ethylenimine) (PEI) w...
Study on the selective hydrogenation of isophorone
Xu, Lei,Sun, Shaoyin,Zhang, Xing,Gao, Haofei,Wang, Wei
, p. 4465 - 4471 (2021/02/03)
3,3,5-Trimethylcyclohexanone (TMCH) is a...
Gas phase transfer hydrogenation of α, β- unsaturated carbonyl compounds into saturated carbonyl compounds over supported Cu catalysts
K, Saidulu Reddy,Enumula, Siva Sankar,Koppadi, Kumara Swamy,Rao Kamaraju, Seetha Rama,Burri, David Raju
, (2019/11/28)
This work aims to produce hydrocinnamald...
Cucurbit[5]uril-mediated electrochemical hydrogenation of α,β-unsaturated ketones
Sales, Ayrlane,de Oliveira e Castro, Isabela Andrade,de Menezes, Frederico Duarte,Selva, Thiago Matheus Guimar?es,Vilar, Márcio
, p. 295 - 305 (2019/09/03)
The potential of cucurbit[5]uril to be u...
Ammonium Tungstate as an Effective Catalyst for Selective Oxidation of Alcohols to Aldehydes or Ketones with Hydrogen Peroxide under Water - A Synergy of Graphene Oxide
Fu, Huihui,Hu, Chuanfeng,Huang, Zhida,Zhou, Jianhao,Peng, Xinhua
supporting information, p. 447 - 451 (2017/11/27)
Ammonium tungstate was found to be a fac...
873-94-9 Process route
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767-54-4
trans-3,3,5-trimethylcyclohexanol
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933-48-2
cis-3,3,5-trimethylcyclohexanol
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-
873-94-9
dihydroisophorone
| Conditions | Yield |
|---|---|
|
With
2,5-dimethyl-2,5-hexanediol; nickel diacetate; sodium hydride; magnesium bromide;
In
tetrahydrofuran;
at 63 ℃;
for 3h;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
|
-
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78-59-1
3,5,5-Trimethylcyclohex-2-en-1-one
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-
767-54-4
trans-3,3,5-trimethylcyclohexanol
-
-
933-48-2
cis-3,3,5-trimethylcyclohexanol
-
-
873-94-9
dihydroisophorone
| Conditions | Yield |
|---|---|
|
With
tetrabutylammonium borohydride;
In
toluene;
at 95 ℃;
for 20h;
Yield given;
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4 % Chromat.
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873-94-9 Upstream products
-
78-59-1
3,5,5-Trimethylcyclohex-2-en-1-one
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64-17-5
ethanol
-
40643-64-9
1-hydroxy-3,3,5-trimethyl-cyclohexanecarbonitrile
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116-02-9
3,3,5-trimethylcyclohexanol
873-94-9 Downstream products
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36101-73-2
di-(3,3,5-trimethylcyclohexyl)amine
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15901-42-5
3,3,5-trimethylcyclohexanamine
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84434-61-7
(1-hydroxy-3,3,5-trimethyl-cyclohexyl)-acetic acid ethyl ester
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77120-09-3
1,3,3,5-tetramethyl-cyclohexanol